Three-stage crude distillation, representing only one of many possible combinations of equipment, is shown schematically in Fig. 3. The process consists of (1) an atmospheric fractionating stage, which produces lighter oils; (2) an initial vacuum stage, which produces well-fractionated, lube oil base stocks plus residue for subsequent propane deasphalting; and (3) a second vacuum stage, which fractionates surplus atmospheric bottoms not applicable for lube production, plus surplus initial vacuum stage residuum not required for deasphalting. This stage adds the capability of removing catalytic cracking stock from surplus bottoms to the distillation unit.
Crude oil is first heated in a simple heat exchanger, then in a direct-fired crude charge heater. Combined liquid and vapor effluent flow from the heater to the atmospheric fractionating tower, where the vaporized distillate is fractionated into gasoline overhead product and as many as four liquid sidestream products: naphtha, kerosene, and light and heavy diesel oil. Part of the reduced crude from the bottom of the atmospheric tower is pumped through a direct-fired heater to the vacuum lube fractionator. Bottoms are combined and charged to a third direct-fired heater. In the tower, the distillate is subsequently condensed and withdrawn as two sidestreams. The two sidestreams are combined to form catalytic cracking feedstocks, and an asphalt base stock is withdrawn from the tower bottom.
Wastewater from crude oil fractionation generally comes from three sources. The first source is the water drawn off from overhead accumulators prior to recirculation or transfer of hydrocarbons to other fractionators. This waste is a major source of sulfides and ammonia, especially when sour crudes are being processed. It also contains significant amounts of oil, chlorides, mercaptans, and phenols.
The second waste source is discharge from oil sampling lines. This should be separable, but it may form emulsions in the sewer.
A third waste source is very stable oil emulsions formed in the barometric condensers used to create the reduced pressures in the vacuum distillation units. However, when barometric condensers are replaced with surface condensers, oil vapors do not come into contact with water and consequently emulsions do not develop.
Was this article helpful?