Filtration

The use of filtration to polish biological treatment system effluent has become more popular in recent years because of more stringent discharge requirements. The 1977 EPA survey of petroleum refineries indicated that 27 of 259 plants used filtration as part of the existing treatment scheme and 16 others planned to install filtration systems in the near future [5]. Filtration can improve effluent quality by removing oil, suspended solids, and associated BOD and COD, and carryover metals that have already been precipitated and flocculated. Improved effluent filtration in one recent instance helped a Colorado refinery to meet the newly adopted discharge toxicity requirements [49].

Granular-medium filters are the predominant type of filtration systems used in refineries. The medium can be sand, dual medium of anthracite and sand, or multimedium of anthracite, sand, and garnet. As the water passes down through a filter, the suspended matter is caught in the pores. When the pressure drop through the filter becomes excessive, the flow is reversed to remove the collected solids. The backwash cycle occurs approximately once a day, depending on the loading, and usually lasts for 10 to 15 minutes. The normal surface loading rate is between 80 and 200 Lpm/sq m (2-5 gpm/sq ft). Coagulants such as iron and aluminum salts and polyelectrolytes can enhance suspended solids removal.

Several advanced filtration systems are finding applications in treating refinery wastewaters. Examples include the HydroClear filter (Zimpro, Rothschild, WI) and the Dynasand filter (Parkson Corporation, Fort Lauderdale, FL). The HydroClear filter employs a single sand medium (0.35-0.45 mm) with an air mix (pulsation) for solids suspension and regeneration of the filter surface. Filter operation enables periodic regeneration of the medium

Rotating Biological Disc
Figure 15 Rotating biological contactors. Plastic discs rotate slowly in a shallow tank. About 60% of each disk is above water surface for aeration. (From Ref. 5.)

surface without backwashing. The Dynasand filter is a continuous self-cleaning upflow deep-bed granular-medium filter [27]. The filter medium is cleaned continuously by recycling the sand internally through an airlift pipe and sand washer. The regenerated sand is redistributed on top of the bed, allowing for a continuous uninterrupted flow of filtered water and reject water.

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