Chemical Reaction Of The Phosphate Ion With Alum

To precipitate the phosphate ion as aluminum phosphate, alum is normally used. The chemical reaction is shown next:

As shown in these reactions, the phosphorus must be in the phosphate form. The reaction occurs in water, so the phosphate ion originates a series of equilibrium orthophosphate reactions with the hydrogen ion. This series is shown as follows (Snoeyink and Jenkins):

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