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" IUPAC recommendation (Atkinson et al., 1997a), based on Roberts and Fajer (1989) and Turberg et al. (1990); the values of Clemitshaw et al. (1997) are in excellent agreement with these.

TABLE 4.20 Recommended Absorption Cross Sections (Base e) of 2-Propyl Nitrate [(CH3)2CH0N02] at Room Temperature"

Wavelength 102"<r Wavelength 102"<r

Solar zenith angle (0)

FIGURE 4.22 Experimental values of the photolysis rate constant, k for (a) ethyl nitrate and (b) «-propyl nitrate as a function of zenith angle compared to calculated values shown by the solid lines. Different symbols represent different measurement days (adapted from Luke et al., 1989).

Solar zenith angle (8)

FIGURE 4.22 Experimental values of the photolysis rate constant, k for (a) ethyl nitrate and (b) «-propyl nitrate as a function of zenith angle compared to calculated values shown by the solid lines. Different symbols represent different measurement days (adapted from Luke et al., 1989).

Wavelength 102"<r Wavelength 102"<r

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