Cccccc

C-C-C-C-C-C C+C-C-C-C-CHO C-C-C-C+C-CHO C-Ç-C-C-C-C c-c-c-c-c-c Ô OH OH

C-C-C-C-C-C C-C+C-C-C-CHO C-C-C+C-C-CHO c-c-c-c-c-c c-c-c-c-c-c

FIGURE 6.1 Possible fates of the 2-hexoxy and 3-hexoxy free radicals (adapted from Eberhard et at., 1995).

C-C-C-C-C-C C-C+C-C-C-CHO C-C-C+C-C-CHO c-c-c-c-c-c c-c-c-c-c-c

FIGURE 6.1 Possible fates of the 2-hexoxy and 3-hexoxy free radicals (adapted from Eberhard et at., 1995).

It should be noted that some alkoxy radicals derived from oxygenated compounds may have some unique chemistry in addition to these reactions. For example, Tuazon et al. (1998b) have shown that alkoxy radicals derived from OH + acetate reactions, i.e., R!C(0)0CH(0')R2, rearrange and decompose to RCO and the acid RC(0)0H.

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